Product ID:SHELL SU-2000(R) SUPER UNLEADED GASOLINE
MSDS Date:11/10/1992
FSC:9130
NIIN:00-148-7104
MSDS Number: BPVMS

SHELL OIL COMPANY

1 SHELL PLAZA
HOUSTON, TX 77001
US

Emergency Phone: 713-473-9461 (24 HOUR EMERGENCY)

Info Phone: 713-241-4819

Preparer: J.C. WILLETT

Cage: 54527

SHELL OIL COMPANY

2463 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0-4%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 0-1%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0-3%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NAPHTHALENE (SARA III)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 0-1%

OSHA PEL 10 PPM/15 STEL

ACGIH TLV: 10 PPM/15 STEL; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ALKANES, CYCLOALKANES, ALKENES AND AROMATIC HYDROCARBONS

Fraction By Weight: BALANCE

LD50 LC50 Mixture:LD50 (RAT) ORAL >5,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION TO
THE NOSE, THROAT AND RESPIRATORY TRACT AND ADDITIONALLY, MAY
PRODUCE LIVER AND KIDNEY DAMAGE. HIGH VAPOR CONCENTRATIONS MAY
PRODUCE CNS DEPRESSION. INGESTION: MAY B E FATAL IF SWALLOWED.
INGESTION MAY RESULT IN VOMITING; ASPIRATION OF VOMITUS INTO LUNGS
MAY RESULT PNEUMONITIS.
Explanation of Carcinogenicity:BENZENE, A COMPONENT OF THIS PRODUCT, IS
CLASSIFIED AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:EARLY TO MODERATE CNS DEPRESSION MAY BE
EVIDENCED BY GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA; IN EXTREME
CASES, UNCONCIOUSNESS AND DEATH MAY OCCUR. ASPIRATION PNEUMONITIS
MAY BE EVIDENCED BY COUGHIN G, LABORED BREATHING AND CYANOSIS.
KIDNEY DAMAGE MAY BE EVIDENCED BY CHANGE IN URINE OUTPUT URINE
APPEARANCE.
Medical Cond Aggravated by Exposure:PREEXISITING EYE, SKIN, AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED. IMPAIRED LIVER AND KIDNEY
FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE.

First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN CONTACT: FLUSH WITH WATER WHILE
REMOVING CONTAMINATED CLOTHING AND SHOES. FOLLOW BY WASHING WITH
SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION
INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED,
RESUSCITATE. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. GET MEDICAL AID.

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER
FOG. DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT ON
WATER.
Fire Fighting Procedures:DANGER. EXTREMELY FLAMMABLE. CLEAR FIRE AREA
OF UNPROTECTED PERSONNEL AND ISOLATE. COOL FIRE EXPOSED CONTAINERS
WITH WATER.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR ACCUMULATING
IN LOW AREAS AND TRAVELING ALONG THE GROUND AWAY FROM THE HANDLING
SITE. DO NOT WELD, HEAT ON OR NEAR CONTAINERS.

Spill Release Procedures:DANGER. EXTREMELY FLAMMABLE. ELIMINATE ALL
IGNITION SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT
SPARKING. ISOLATE THE HAZARD AREA. WEAR APPROPRIATE RESPIRATOR AND
PROTECTIVE CLOTHING. WATE R FOG MAY BE USEFUL IN SUPPRESSING VAPOR
CLOUD.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:USE EXPLOSION-PROOF VENTILATION AS
REQUIRED TO CONTROL VAPOR CONCENTRATIONS. DO NOT USE AS A CLEANING
SOLVENT OR FOR OTHER NON-MOTOR FUEL USES.
Other Precautions:IF A MAJOR SPILL OCCURS, GET UPWIND AND NOTIFY LOCAL
EMERGENCY PERSONNEL. EXPLOSION AND FIRE IS THE MOST IMMEDIATE
DANGER. HARMFUL OR FATAL IF SWALLOWED. DO NOT SIPHON GASOLINE BY
MOUTH.

Respiratory Protection:UNDER CONDITIONS OF POTENTIAL HIGH EXPOSURE, THE
USE OF A NIOSH-APPROVED RESPIRATOR IS RECOMMENDED. USE EITHER AN
ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR PURIFYING RESPIRATOR FOR
ORGANIC VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:NITRILE RUBBER OR VITON/NEOPRENE
Eye Protection:FACE SHIELD AND GOGGLES OR CHEMICAL GOGS
Other Protective Equipment:STANDARD WORK CLOTHING. SHOES CONTAMINATED
WITH THIS PRODUCT THAT CAN NOT BE DECONTAMINATED SHOULD BE
DISCARDED.
Work Hygienic Practices:WEAR IMPERVIOUS GLOVES WHEN "DIP-STICKING
STORAGE TANKS". WORK UPWIND OF SMALL SPILLS.
Supplemental Safety and Health
DO NOT USE THIS PRODUCT AS A SOLVENT FOR CLEANING EQUIPMENT OR SKIN.
STORE SMALL QUANTITIES ONLY IN SAFETY CANS. ALLOW CONTAMINATED RAGS
TO DRY IN WELL-VENTILATED AREA BEFORE STORAGE. PRODUCT SPREADS
EASILY AND MAY FLASH BACK ALONG VAPOR TRAILS. PRODUCT NAME HAS BEEN
CHANGED, FORMERLY SU 2000 (SUPER UNLEADED GASOLINE).

HCC:F2
Vapor Pres:7-14.5
Vapor Density:3.5(AIR=1)
Spec Gravity:0.72-0.76
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE COLOR, CLEAR AND BRIGHT LIQUID. HYDROCARBON
ODOR.
Percent Volatiles by Volume:100 %

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES. PREVENT VAPOR
ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS.

Waste Disposal Methods:UNDER EPA-RCRA, IF THIS PRODUCT BECOMES A WASTE
MATERIAL, IT WOULD BE AN IGNITABLE HAZARDOUS WASTE NUMBER D001.
REFER TO LATEST EPA OR STATE REGULATIONS FOR PROPER DISPOSAL. THIS
PRODUCT CONTAINS BENZ ENE AT >0.5 MG/L

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.